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Summary of Carbohydrate :-
Carbohydrates, because the name suggest, were defined as a group of compounds composed of carbon, hydrogen and oxygen during which the latter two elements are within the same proportion as in water and were expressed by a formula (CH2 O)n , that is, hydrates of carbon.The term ‘carbohydrates’ arose from the mistaken belief
that substances of this sort were hydrates of carbon,
because the formula of the many substances could
be expressed within the form CX(H2
O)Y
, as an example, glucose
(C6
H12 O6
), sucrose (C12 H22 O11), etc. In these examples,
the hydrogen and oxygen are present within the same ratio
as in water. But this definition has certain drawbacks as
given below:
It should be kept in mind that every one organic compounds
containing hydrogen and oxygen within the proportion
found in water don't seem to be carbohydrates. as an example,
formaldehyde HCHO for the current purpose written
as C(H2
O); ethanoic acid CH3
COOH written as C3
(H2
O)2
;
and carboxylic acid CH3
CHOHCOOH written as C3
(H2
O)3
are not carbohydrates.
Also, an oversized number of carbohydrates like rhamnose
(C6
H12O5
), cymarose (C7
H14O4
), digitoxose (C6
H12O4
),
etc., are known which don't contain the same old proportions of hydrogen to oxygen.
Finally, certain carbohydrates also are known which
contain nitrogen or sulphur additionally to carbon, hydrogen and oxygen.
From the above discussion, it will be concluded that
the definitions described above don't seem to be correct; however,
carbohydrates are now defined chemically as polyhydroxy
aldehyde or polyhydroxy ketones or compound that on
hydrolyses produce either of the above.
Carbohydrates are among the primary products to arise as a
result of photosynthesis.
They constitute an outsized proportion
of the plant biomass and are responsible, as cellulose, for
the rigid cellular framework and, as starch, for providing
an important food reserve. Of special pharmacognostical
importance is that the undeniable fact that sugars unites with a good variety
of other compounds to make glycosides and secondary
metabolites. Mucilage, as found in marshmallow root and
psyllium seeds, act as water-retaining vehicles, where as
gums and mucilage, which are similar in composition and
properties, are formed within the plant by injury or stress and
usually appear as solidified exudates; both are typically
composed of uronic acid and sugar units.
The cell walls
of the brown seaweeds and therefore the middle lamellae of upper
plant tissues contain polysaccharides consisting almost
entirely of uronic acid components.
Low relative molecular mass carbohydrates are crystalline,
soluble in water and sweet in taste, as an example, glucose,
fructose, sucrose, etc. The high relative molecular mass carbohydrates (polymers) are amorphous, tasteless and comparatively
less soluble in water, as an example, starch, cellulose, inulin,
etc.
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